M4.
decorating plastic
parts with processes that are also common to non-plastics
– Silk screening, roll
coating, electroplating, labeling (except in-mold labeling described below),
laser marking, flocking, dyeing, vacuum metalizing, sputtering, polishing and
buffing are all described in Chapter 8 of this handbook. Printing (various
processes) is described in chapter 9. Polishing and buffing operations for
thermoplastics must be carried out with softer wheels, slower speeds and
lighter pressures than with metal parts, to avoid overheating the surface of
the workpiece.
M4a.
electroplating of
plastics
-
A number of plastics can be electroplated by being treated to make the surface
conductive before the plating operation. One way to do this is to plate the
part by the electroless method with a thin layer; electroless plating can be
used with non-conductive materials. Another approach is to add carbon to the
plastic when the part is molded. A third method is to coat the workpiece with a
conductive paint. The electroless method involves several steps: 1) acid
etching to create a microporous surface, 2) a neutralizer bath to reduce any
residual acid, 3) a catalyst bath to deposit palladium in the surface
micropores, 4) an accelerator bath to prepare the palladium for electroless
plating and, 5) electroless plating with either copper or a nickel-phosphorous
alloy. The conductive part is then plated by conventional methods. ABS and PEC
(polyphenylene ether copolymer) are the most frequently plated plastics, but
polystyrene, ABS/polycarbonate, nylon and polysulfone are also processed.
Automotive hardware and trim are often made from plated plastic moldings. A
major application is the plating of the circuit paths on printed circuit
boards. Epoxy/glass, polyimide, phenolic and Teflon/glass are common substrates.
The plating of household faucets, knobs, marine hardware, hospital equipment
and kitchenware are other uses.
M5.
in-mold decorating
- It is quite feasible to
place decorative or other material in a mold so that the item, after molding,
is integral with the molded part. Several alternative methods are possible: 1)
The mold cavity walls can be coated with another material prior to molding to
provide a surface finish on the molded part different from that which would
otherwise be achieved. Both liquid and powder coatings are used. 2) product
labels can be inserted in a mold before the molding operation and, 3)
decorative foils or other objects can also be placed in the mold so that they
become part of the finished product. This approach is feasible with injection
molding, compression molding, RIM and other molding processes, including those
carried out with reinforced plastics. The advantage with coatings is that they
eliminate surface porosity, and provide a durable, smooth surface for the part.
The advantage with inserted foils and labels is that the inserted object is
securely held and, in some cases, increases the strength of the finished
part while reducing the amount of material required. The need for later
finishing operations is often reduced. Foils with a brushed aluminum or wood
grained appearance are common inserts. The inserting operation at the molding
machine can be manual or, in many cases, robotic. One early and still common
in-mold decorating operation is the use of preprinted, resin-impregnated paper
in the molding of melamine dishes and urea and phenolic products.
Thermoplastics can also be processed with decorative inserts. Polypropylene,
polyethylene, polystyrene, polycarbonate, ABS and acrylics are suitable for
in-mold label and foil decorating.
M6.
sheet and film
embossing
-
Several methods are used to produce textures in the surfaces of plastic film
and sheet. Such textures change the appearance of the sheet, provide a
different feel and can hide other imperfections. One common example of a
changed surface of sheet plastic is the modification of flexible vinyl sheets
to provide a leather-like appearance. The common method for producing this
effect is to run the heated sheet through a pair of cooled forming rolls. At
least one of the rolls is engraved with the reverse of the pattern desired on
the plastic sheet. When passed through the rollers, the sheet is formed and
then cooled so that the texture becomes permanent. Depending on the results
wanted, the roll used to back up the engraved roll can be rubber or another
resilient material. It can be flat steel or can be engraved to better emboss
the sheet or provide some other pattern on the reverse side. Although it is
most common to have a heated sheet and cool rolls, sometimes, the sheet is
initially cool and is formed by rolls that are heated. Still another method
uses formed paper, with a release agent on its surface, in a film casting
operation so that the film or sheet as initially made has the texture in it.
Sometimes, when deep embossing is desired, the roll is porous and a vacuum is
drawn in it. Other methods involve dielectric or frictional heating in small
areas of the sheet to aid in forming.
Forming or embossing is sometimes combined with
printing a pattern on the surface to enhance the appearance of the texture.
Valley printing
, that is, printing in the
depressed parts of the surface, is illustrated in Fig. 4M6 which shows
equipment that embosses and prints the surface in the same operation. This
approach is useful in imparting wood grain, textile or leather effects on
vinyl, urethane or
other plastic sheets.
Fig.
4M6 Valley
embossing and printing of film or sheet.
2
a) Valley printing -
printing in the depressed areas of an embossed sheet. b) Schematic view of
combination embossing and valley printing equipment: A - patterned applicator
rolls, B - analox rolls, C - doctor blade to remove excess ink, D - ink pan, E
– furnisher roll.