H1b.
continuous casting of
sheet
-
uses a pair of moving, parallel, highly-polished, and endless, stainless steel
belts, between which is poured or pumped an acrylic syrup similar, but not
identical, to that used for cell casting of acrylic as described above. (The
material mixture may be varied in order to provide the proper viscosity for the
method used. The final sheet, though a thermoplastic, will contain some
cross-linked material to improve chemical and stain resistance and
thermo-formability.) Flexible gaskets at the edges of the sheets prevent
leakage. The stainless steel belts convey the material through a heating phase
to induce polymerization, followed by a quick cooling phase to prevent bubbling
of the material. Another heating phase up to about 260
°
F (125
°
C)
is then used to complete the polymerization to the desired level. Then the
solid product exits the belt system, the surfaces are covered with a protective
film and sheets are cut to the length desired. Fig. 4H1b illustrates the
process. The equipment required is rather large and expensive but output rates
are high. Most acrylic sheet is produced by the continuous casting method.
Sheet thicknesses can range from about 0.080 to 0.500 in (2 to 12.5 mm).
Applications are the same as those for cell cast sheet except that optical
properties are not as good as those from cell casting. Skylights, sign
components, and glazing are all applications for continuous cast acrylic sheet.
Fig. 4H1b Schematic view of
equipment used for the continuous casting of acrylic sheet. The acrylic syrup
is spread and compressed between two polished stainless steel belts, which carry
it through a series of ovens that polymerize the acrylic by heating, cooling,
and reheating to produce a solid cast sheet. (Note: For convenience of
illustration, the heating and cooling zones are shown much shorter than those
in actual production equipment.)
H2.
casting structural foam
parts
-
is simply reaction injection molding (as discussed above in 4C3b) performed on
a manual basis. Liquid components of thermosetting resins (usually
polyurethane) are mixed and poured into a mold. Polymerization and foaming take
place in the mold. Heated molds are used to accelerate polymerization. Oven
curing usually takes place after casting. This process is particularly
applicable to prototypes and limited quantity production, and can be used
effectively for large plastic parts.
H3.
casting nylon parts
- Cast nylon has superior
machinability, stiffness and heat deflection properties than nylon 6/6 which is
injection molded or extruded. The nylon casting process involves use of the
monomer; polymerization takes place in the mold. The monomer must be heated and
melted before casting, and must be protected against moisture absorption during
the casting sequence since it is highly hygroscopic. Sealed containers and
inert atmospheres may be used to prevent moisture from coming in contact with
the material. Molds can be inexpensive since the forces they are subjected to
are low. Aluminum, epoxy, and silicone rubber, as well as steel, have been used
as mold materials. The casting operation often takes place in heated ovens.
(The monomer material is heated to 390
°
F
(200
°
C). For smaller parts,
centrifugal casting may be employed, i.e., the molds are spun to provide
sufficient force to fully fill the mold cavities. Cooling of finished parts is
slow to permit relief of internal stresses from shrinkage (15%). Large parts
(up to 400 lbs
−
180 Kg) can be
produced with the process. Gears, sheaves, cams, various machine parts,
bushings, and bearings are common applications. The casting process lends
itself well to low-quantity production levels.
H4.
casting acrylic parts
- The same kind of
monomer-polymer mixture used in cell casting of acrylic sheets (See H1a above)
can produce shaped parts if a suitable mold is used. The process is useful at
low production quantities when the cost of an injection mold and molding
machine cannot be justified. The optical clarity of acrylic makes it useful for
embedding an object or biological specimen in a clear protective or decorative
block. Embedded objects are pre-positioned in the mold before casting. Molds
can be made of almost any material because the operation does not require
elevated temperatures. Art statuary, and marble-like kitchen and bathroom
counters and sinks are other applications. When marble-like objects are cast,
the acrylic is mixed with up to 60% of inorganic filler which gives the
appearance of marble.
H5.
encapsulation and
potting
-
various electronic and electrical devices are encapsulated with plastics to
provide insulation, and mechanical and environmental protection. Potting
involves partly surrounding a device with plastic to fix it in place in some
component. Both encapsulation and potting involve casting, usually with
thermosets. Epoxy potting of small transformers for electronic devices is a
common example of potting. High voltage transformers are frequently potted with
silicone rubber. As with regular casting, simple molds can be used. Often,
immediately after casting, the filled mold is placed in a vacuum chamber so
that any trapped gases or air will bubble out of the liquid casting resin
before it sets. This procedure eliminates or minimizes voids in the cured
material.